Examination of Synthetic Routes to Monosubstituted Diimides. II. Synthesis of t-Butyl Aryl-and Acylazoformates. Acid-Induced Cleavage of the Thionocarbo-t-butoxy …

LA Carpino, PH Terry, PJ Crowley

Index: Carpino,L.A. et al. Journal of Organic Chemistry, 1961 , vol. 26, p. 4336 - 4340

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Citation Number: 46

Abstract

tButjyl% substituted carbaeates have been prepared by acylation of substituted phenylhydrazines by meana of t-butyl azidofonnate in pyridine or by alkylation or acvlation of t-butyl carbazate. Oxidation of the appropriate hydrazo derivatives by means of N- bromosuccinimide and pyridine gave t-butyl phenyl-, p-bromophenyl-, pnitrophenyl-, emethoxyphenyland benwylazoformates. &Butyl hydrazodifomate gave t-butyl ...