Synthesis and Chemistry of 1H-Cyclobuta [de] naphthalenes, 1-Alkylidene-1H-cyclobuta [de] naphthalenes, and 1H-Cyclobuta [de] naphthalen-1-one

PJ Card, FE Friedli, H Shechter

Index: Card,P.J.; Friedli,F.E.; Shechter,H. Journal of the American Chemical Society, 1983 , vol. 105, p. 6104

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Citation Number: 10

Abstract

Abstract: Grignard and lithium reagents from 1-bromo-lH-cyclobuta [de] naphthalene (la) are converted by protonic acids, trimethylsilyl chloride, methyl iodide, carbon dioxide, acetyl chloride, and ethylene oxide to the corresponding lH-cyclobuta [de] naphthalene derivatives. Further, displacements of la by various nucleophiles (aluminohydrides, iodide, chloride, cyanide, azide, methoxide and thiophenoxide, triphenylphosphine, silver nitrate, acetate, ...

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