Kinetic investigation of oxidation of aromatic anils by potassium peroxymonosulfate in aqueous acidic medium

R Venkatesh, K Karunakaran

Index: Venkatesh; Karunakaran International Journal of Chemical Kinetics, 2013 , vol. 45, # 8 p. 542 - 550

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Citation Number: 4

Abstract

ABSTRACT The kinetics of oxidation of aromatic anils to benzaldehyde and azobenzene by potassium peroxymonosulfate has been studied in aqueous acetic acid medium. The low dielectric constant of the medium facilitates the reactivity. It has been found that the variation in the ionic strength of the reaction has a negligible effect on the rate. Similarly, polymerization was not observed when acrylonitrile was added to the reaction mixture. ...

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