Chemistry Letters

PHOTOCHEMISTRY OF DIBENZO-1, 1, 2, 2, 3, 3-HEXAMETHYL-1, 2, 3-TRISILACYCLOHEPTA-4, 6-DIENE AND THE GERMANIUM ANALOG. GENERATION OF …

H Sakurai, K Sakamoto, M Kira

Index: Sakurai, Hideki; Sakamoto, Kenkichi; Kira, Mitsuo Chemistry Letters, 1984 , p. 1379 - 1382

Full Text: HTML

Citation Number: 31

Abstract

Photolysis of the title compound afforded silafluorene and dibenzo-1, 2- disilacyclohexadiene as primary photoproducts. Two reactive intermediates, tetramethyldisilene and dimethylsilylene, were detected by trapping. The dimethylgermylene, derived from the germanium analog, was first observed by electronic spectra.

Related Articles:

Photochemical reactions of vinyl-, styryl-, and benzyl-substituted digermanes

[Mochida, Kunio; Kikkawa, Haruhiko; Nakadaira, Yasuhiro Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 9 p. 2772 - 2777]

Photochemistry of dibenzo-1, 1, 2, 2-tetramethyl-1, 2-disilacyclohexa-3, 5-diene and the germanium analog. Exclusive extrusion of the divalent species

[Kira,M.; Sakamoto,K.; Sakurai,H. Journal of the American Chemical Society, 1983 , vol. 105, p. 7469]

Chemie der schweren Carben-Analogen R2M, M Si, Ge, Sn: XV. Synthese neuer Spiro-Germanium-Verbindungen durch 1, 4-Cycloaddition von cyclischem Diamino …

[Billeb, G.; Bootz, K.; Neumann, W. P.; Steinhoff, G. Journal of Organometallic Chemistry, 1991 , vol. 406, # 3 p. 303 - 308]

Electronic absorption spectra of diorganogermylenes in matrixes: formation of diorganogermylene complexes with heteroatom-containing substrates

[Ando, Wataru; Itoh, Hiroyuki; Tsumuraya, Takeshi Organometallics, 1989 , vol. 8, p. 2759 - 2766]

New photochemical routes to germylenes and germenes and kinetic evidence concerning the germylene-diene addition mechanism

[Bobbitt, Kevin L.; Maloney, Vincent M.; Gaspar, Peter P. Organometallics, 1991 , vol. 10, p. 2772 - 2777]

More Articles...