Elimination of hydrogen fluoride from fluorinated succinic acids.(II) Kinetics of dehydrofluorination of fluoro-, 2, 2-difluoro-, meso-and DL-2, 3-difluoro-, and …
M Hudlicky, TE Glass
Index: Hudlicky, M.; Glass, T. E. Journal of Fluorine Chemistry, 1983 , vol. 23, p. 15 - 28
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Citation Number: 4
Abstract
Abstract Elimination of hydrogen fluoride from fluorosuccinic acid gave fumaric acid, from 2, 2-difluorosuccinic acid, meso-and DL-2, 3-difluorosuccinic acid fluorofumaric acid, and dehydrofluorination of trifluorosuccinic acid afforded difluoromaleic acid. Kinetic data based on 1 H NMR measurements are presented for temperatures of 60, 75 and 90. All the dehydrofluorinations follow second order kinetics. Activation energies for the ...
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