Tetrahedron letters

Organomanga+ nese (II) reagents XIV 1: A short and efficient synthesis of diastereoisomeric (±)-α-bisabolols and (±)-chlorphenoxamine

G Cahiez, J Rivas-Enterrios, P Clery

Index: Cahiez, Gerard; Rivas-Enterrios, Jose; Clery, Patrick Tetrahedron Letters, 1988 , vol. 29, # 30 p. 3659 - 3662

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Citation Number: 17

Abstract

Abstract Diastereoisomeric (±)-α-bisabolols (7), a sesquiterpenoid alcohol, and (±)- chlorphenoxamine (12), an antihistamine, have been prepared in excellent yields, Both these short and convenient syntheses involve as a key step the one-pot elaboration of a dissymmetrical tertiary alcohol via an organomanganese reagent (5 to 7 and 9 to 10 respectively).

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