The Journal of Organic Chemistry

The ortho-Claisen Rearrangement. V. The Products of Rearrangement of Allyl mX-Phenyl Ethers1

WN WHITE, CD SLATER

Index: White,W.N.; Slater,C.D. Journal of Organic Chemistry, 1961 , vol. 26, p. 3631 - 3638

Full Text: HTML

Citation Number: 26

Abstract

The effect of substituents on the rearrangement of allyl aryl ethers has been investigated extensi~ ely.~-7 These studies have led to a definition of the stereochemical'and electrical6 nature of the transition state of this rearrangement. However, the isomerization of allyl mX- phenyl ethers has not been systematically examined, and the scanty information which is n~ ailable5 indicates thesc compounds may behave soniewhat anomalously. Therefore, it ...