Fragmentation of anion radicals with elimination of aryloxy groups
AS Dneprovskii, IV Fedosov
Index: Dneprovskii; Fedosov Russian Journal of Organic Chemistry, 2001 , vol. 37, # 10 p. 1438 - 1443
Full Text: HTML
Citation Number: 2
Abstract
Abstract 4-Vinylbenzyl phenyl ether, 4-phenylbenzyl phenyl ether, 1-and 2-naphthylmethyl phenyl ethers react with sodium thiophenolate under photochemical stimulation with replacement of the phenoxy group. The composition of reaction products and relation of reactivity to the structure of substrates is consistent with anion-radical mechanism. The corresponding methoxy and cyano derivatives do not undergo the reaction.
Related Articles:
[Kangani, Cyrous O.; Day, Billy W.; Kelley, David E. Tetrahedron Letters, 2008 , vol. 49, # 5 p. 914 - 918]
Synthesis of 7-cyano-and 7-acetamido-indoles via cyanocarbonation/hydrogenation of 7-formyl indole
[Kolis, Stanley P.; Clayton, Marcella T.; Grutsch, John L.; Faul, Margaret M. Tetrahedron Letters, 2003 , vol. 44, # 30 p. 5707 - 5710]
[Huber, Vincent J.; Bartsch, Richard A. Tetrahedron, 1998 , vol. 54, # 32 p. 9281 - 9288]
Oxidant-free conversion of primary amines to nitriles
[Velcicky, Juraj; Soicke, Arne; Steiner, Roland; Schmalz, Hans-Guenther Journal of the American Chemical Society, 2011 , vol. 133, # 18 p. 6948 - 6951]
Oxidant-free conversion of primary amines to nitriles
[Velcicky, Juraj; Soicke, Arne; Steiner, Roland; Schmalz, Hans-Guenther Journal of the American Chemical Society, 2011 , vol. 133, # 18 p. 6948 - 6951]