Organic Letters 2004-06-10

SimplePHOX, a readily available chiral ligand system for iridium-catalyzed asymmetric hydrogenation.

Sebastian P Smidt, Frederik Menges, Andreas Pfaltz

Index: Org. Lett. 6 , 2023-2026, (2004)

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Abstract

[reaction: see text] New Ir-SimplePHOX complexes Ir-6-Ir-9 catalyze the quantitative, highly enantioselective hydrogenation of a range of unfunctionalized and functionalized olefins. Synthesis, catalytic results, and X-ray crystal structures are presented here.

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