Revisitation of Formaldehyde Aniline Condensation. VII. 1, 3, 5??Triarylhexahydro??sym??triazines and 1, 3, 5, 7??Tetraaryl??1, 3, 5, 7??tetrazocines from Aromatic Amines …

AG Giumanini, G Verardo, E Zangrando…

Index: Giumanini, Angelo G.; Verardo, Giancarlo; Zangrando, Ennio; Lassiani, Lucia Journal fuer Praktische Chemie (Leipzig), 1987 , vol. 329, # 6 p. 1087 - 1103

Full Text: HTML

Citation Number: 1

Abstract

Abstract A product study of the reaction between a number of aromatic amines substituted with widely different groups and paraformaldehyde in inert solvents was performed and found to yield 1, 3, 5-triaryl-1, 3, 5-hexahydrotriazines, 1, 3, 5, 7-tetraaryl-1, 3, 5, 7- tetrazocines and formaminals. It was not possible to correlate the product outcomes with the actual structure of the amine substrate. The X-ray diffraction structural determination of 1, 3 ...