Hochdruckversuche—X11IX. Mitt. R. Mündnich und H. Plieninger. Tetrahedron im Druck.: Enantioselektive wagner-meerwein umlagerung in chiralen lösungsmitteln …
HP Kraemer, H Plieninger
Index: Kraemer,H.P.; Plieninger,H. Tetrahedron, 1978 , vol. 34, p. 891 - 896
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Citation Number: 6
Abstract
In the Wagner-Meerwein rearrangement of 1, 1-Diphenyl-2-methyl-2-(4-methoxyphenyl) oxiran 1 an enantioselektive synthesis takes place in chiral solvents only at high pressure. The asymmetric induction reaches up to 14-proz. depend on the chiral solvent. A pressuie dependency of the product distribution also is reported.
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