Electron transfer processes. Reactions of 5-nitrofuryl derivatives going by anionradical mechanism

J Prousek

Index: Prousek, Josef Collection of Czechoslovak Chemical Communications, 1980 , vol. 45, # 12 p. 3347 - 3353

Full Text: HTML

Citation Number: 10

Abstract

Abstract 5-Nitrofurfuryl nitrate and bromide (Ia, b) react with electron donors to give 1, 2-bis (5-nitro-2-furyl) ethane (II), 1, 2-bis (5-nitro-2-furyl) ethylene (III), 5-nitro-2-methylfurane (IV), products of S RN 1 reactions Va, Vb and other derivatives. Formation of the derivatives II to V is discussed on the basis of anionradical mechanism. 4-Nitrobenzyl bromide reacts by a S RN 1 reaction with 5-nitrofurfuryl phenyl sulphone (Va) in basic medium to give 1-(5-nitro- ...

Related Articles:

2-Chloro-5-methylfuran and 2-Methyl-5-nitrofuran

[Gilman; Wright Journal of the American Chemical Society, 1932 , vol. 54, p. 4108]

Reaction of nucleophiles with electron acceptors by S n 2 or single electron transfer (SET) mechanisms: thiolates and 2-halomethyl-5-nitrofurans.

[Beadle, Charles D.; Bowman, W. Russell; Prousek, Josef Tetrahedron Letters, 1984 , vol. 25, # 43 p. 4979 - 4982]

Reaction of nucleophiles with electron acceptors by S n 2 or single electron transfer (SET) mechanisms: thiolates and 2-halomethyl-5-nitrofurans.

[Beadle, Charles D.; Bowman, W. Russell; Prousek, Josef Tetrahedron Letters, 1984 , vol. 25, # 43 p. 4979 - 4982]

Reaction of nucleophiles with electron acceptors by S n 2 or single electron transfer (SET) mechanisms: thiolates and 2-halomethyl-5-nitrofurans.

[Beadle, Charles D.; Bowman, W. Russell; Prousek, Josef Tetrahedron Letters, 1984 , vol. 25, # 43 p. 4979 - 4982]

Reaction of nucleophiles with electron acceptors by S n 2 or single electron transfer (SET) mechanisms: thiolates and 2-halomethyl-5-nitrofurans.

[Beadle, Charles D.; Bowman, W. Russell; Prousek, Josef Tetrahedron Letters, 1984 , vol. 25, # 43 p. 4979 - 4982]

More Articles...