Peroxovanadium-catalyzed oxidative esterification of aldehydes
R Gopinath, B Barkakaty, B Talukdar…
Index: Gopinath, Rangam; Barkakaty, Balaka; Talukdar, Bandana; Patel, Bhisma K. Journal of Organic Chemistry, 2003 , vol. 68, # 7 p. 2944 - 2947
Full Text: HTML
Citation Number: 84
Abstract
The peroxovanadium species generated from V2O5 and hydrogen peroxide, which is liberated from peroxy salts such as sodium perborate (SPB) or sodium percarbonate (SPC), transform aldehydes directly into esters in an alcoholic medium. Monoesters of diols have been achieved directly in one pot from aldehydes. High catalytic turnover number combined with inexpensive, easily available reagents and innocuous side products from the reaction ...
Related Articles:
Efficient and chemoselective alkyl bromoacetate–Zn mediated transesterification method
[Coskun, Necdet; Er, Mustafa Tetrahedron, 2003 , vol. 59, # 19 p. 3481 - 3485]
A highly selective methodology for the direct conversion of acetals to esters
[Chidambaram, N.; Bhat, Shridhar; Chandrasekaran, S. Journal of Organic Chemistry, 1992 , vol. 57, # 18 p. 5013 - 5015]
[Jagadeesh, Rajenahally V.; Junge, Henrik; Pohl, Marga-Martina; Radnik, Joerg; Brueckner, Angelika; Beller, Matthias Journal of the American Chemical Society, 2013 , vol. 135, # 29 p. 10776 - 10782]
[Cao, Yu-Qing; Wu, Guo-Qiang; Li, Ya-Bin; Dai, Zhi; Chen, Bao-Hua Synthetic Communications, 2006 , vol. 36, # 22 p. 3353 - 3358]
[Journal of the American Chemical Society, , vol. 105, # 23 p. 6935 - 6941]