Diels-Alder chemistry of graphite and graphene: graphene as diene and dienophile.
Santanu Sarkar, Elena Bekyarova, Sandip Niyogi, Robert C Haddon
Index: J. Am. Chem. Soc. 133(10) , 3324-7, (2011)
Full Text: HTML
Abstract
The zero-band-gap electronic structure of graphene enables it to function as either the diene or the dienophile in the Diels-Alder reaction, and this versatile synthetic method offers a powerful strategy for the reversible modification of the electronic properties of graphene under very mild conditions.
Related Compounds
Related Articles:
2003-11-28
[J. Org. Chem. 68(24) , 9263-8, (2003)]
Organic chemistry of graphene: the Diels-Alder reaction.
2013-11-11
[Chemistry 19(46) , 15719-25, (2013)]
Total synthesis of the novel benzopentathiepin varacinium trifluoroacetate: the viability of" varacin-free base. Behar V, et al.
[J. Am. Chem. Soc. 115(15) , 7017-18, (1993)]
Vinyl ether hydrolysis. XVIII. The two-stage reaction of 2,3-dimethoxy-1,3-butadiene. Kresge AJ and Yin Y.
[Can. J. Chem. 65(8) , 1753-1756, (1987)]
Simple one-step synthesis of 3,4-dimethoxythiophene and its conversion into 3, 4-ethylenedioxythiophene (EDOT). von Kieseritzky F, et al.
[Tetrahedron Lett. 45(31) , 6049-6050, (2004)]