Some Reactions of Triphenyltinlithium and Triphenylleadlithium

H Gilman, OL Marrs, SY Sim

Index: Gmelin Handbook: Sn: Org.Verb.1, 1.1.1.16.1.1, page 141 - 147 Full Text Show Details Gilman, H.; Marrs, O. L.; Sim, S. Y. Journal of Organic Chemistry, 1962 , vol. 27, p. 4232 - 4236

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Citation Number: 38

Abstract

Homogeneous solutions of triphenyltin-and triphenylleadlithium have been prepared from the corresponding chloride and lithium in tetrahydrofuran. Hexaphenylditin has been cleaved to give good yields of the tin-lithium derivative. This triphenyltinlithium reacted with water and carbon dioxide to give only hexaphenylditin. In contrast to the benzoic acid obtained from carbonation of the triphenylleadlithium prepared from lead dichloride and ...