Vinyl Derivatives of the Metals. VI. Preparation, Properties and Some Reactions of Trivinyl Compounds of Group V Elements1, 2

…, D Seyferth, FGA Stone, EG Rochow

Index: Maier, L.; Seyfert, D.; Stone, F. G. A.; Rochow, E. G. Journal of the American Chemical Society, 1957 , vol. 79, p. 5884 - 5889

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Citation Number: 58

Abstract

Trivinyl compounds of Group V elements have been prepared by the reaction between vinyl Grignard reagent and the appropriate trihalide. Some physical properties of these trivinyl derivatives are reported, and several new addition compqunds of the type [(CH,: CH) aRMv] X are described. The ability to form" onium" type adducts decreases in passing from trivinylphosphine to triv~ nylblsmuth. Trivinylarsine and-stibine form complex compounds [ ...