Synlett

Azide-mediated detosylation of N-tosylpyrroloiminoquinones and N-tosylindole-4, 7-quinones

SP Patel, DH Nadkarni, S Murugesan, JR King…

Index: Patel, Swayamprabha P.; Nadkarni, Dwayaja H.; Murugesan, Srinivasan; King, Jason R.; Velu, Sadanandan E. Synlett, 2008 , # 18 p. 2864 - 2868

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Citation Number: 3

Abstract

Abstract The utility of NaN 3 as a reagent for the detosylation of N-tosylpyrroloiminoquinones and N-tosylindole-4, 7-quinones is described. The NaN 3-mediated detosylation is carried out in polar aprotic solvents such as DMF and DMSO. The reaction occurs under neutral, mild conditions and results in good to excellent yields of the detosylated quinones.

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