The Journal of Organic Chemistry

Long Chain Alkanoic and Alkenoic Acids with Perfluoroalkyl Terminal Segments1

NO Brace

Index: Brace,N.O. Journal of Organic Chemistry, 1962 , vol. 27, p. 4491 - 4498

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Citation Number: 157

Abstract

Results Peroxide-or azonitrile-induced addition at 80-150'of iodoperfluoroalkanes to unsaturated acids proved to be far superior to thermally or ultraviolet light-induced reactions.” The initial adduct was obtained in excellent yield and high conversion in a short reaction time; those listed in Table I were distilled or crystallized. In most cases the rather sensitive iodo compound was not purified further but was converted directly to the solid, ...