CuI-catalyzed intramolecular O-vinylation of carbonyl compounds.
Yewen Fang, Chaozhong Li
Index: Chem. Commun. (Camb.) (28) , 3574-6, (2005)
Full Text: HTML
Abstract
The first copper-catalyzed intramolecular O-vinylation of carbonyl compounds with vinyl bromides was reported, among which the efficient formation of 5-, 6- and even 7-membered cyclic alkenyl ethers was achieved with beta-ketoesters as nucleophiles.
Related Compounds
Related Articles:
Reactivity in nucleophilic vinylic substitution (S(N)V):S(N)Vπ versus S(N)Vσ mechanistic dichotomy.
2013-09-06
[J. Org. Chem. 78(17) , 8574-84, (2013)]
Asymmetric synthesis of enantioenriched (+)-elaeokanine A.
2006-07-21
[J. Org. Chem. 71(15) , 5674-8, (2006)]
2013-01-21
[Angew. Chem. Int. Ed. Engl. 52(4) , 1266-9, (2013)]
Total synthesis of polycavernoside A, a lethal toxin of the red alga Polycavernosa tsudai.
2005-07-08
[J. Org. Chem. 70(14) , 5449-60, (2005)]
Synthesis of the C1-C13 tetraenoate subunit of the chivosazoles.
2010-08-20
[Org. Lett. 12(16) , 3724-7, (2010)]