Tetrahedron Letters

Chemoselective sulfide oxidation mediated by bridged flavinium organocatalysts

BJ Marsh, DR Carbery

Index: Marsh, Barrie J.; Carbery, David R. Tetrahedron Letters, 2010 , vol. 51, # 17 p. 2362 - 2365

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Citation Number: 32

Abstract

The chemoselective oxidation of sulfides to sulfoxides, catalysed by bridged, tetracyclic flavinium catalysts is presented. The flavinium catalysts are easily prepared via a telescoped three-step process. A range of sulfoxides is accessed in excellent yield and chemoselectivity.

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