Catalytic and Chemoselective Oxidation of Activated Alcohols and Direct Conversion of Diols to Lactones with In Situ??Generated Bis??IBX Catalyst

S Seth, S Jhulki, JN Moorthy

Index: Seth, Saona; Jhulki, Samik; Moorthy, Jarugu Narasimha European Journal of Organic Chemistry, 2013 , # 12 p. 2445 - 2452

Full Text: HTML

Citation Number: 8

Abstract

Abstract The twisted 3, 3′-diiodo-2, 2′, 6, 6′-tetramethoxybiphenyl-4, 4′-dicarboxylic acid (DIDA) was designed and synthesized for the in situ generation of Bis-IBX and catalytic oxidations. The seemingly better solubility of the in situ-generated Bis-IBX and the attenuated reactivity arising from its unique structural features and methoxy substituents allowed the catalytic oxidation of activated alcohols selectively using DIDA/oxone. ...

Related Articles:

A mild and efficient biomimetic synthesis of α-hydroxymethylarylketones from oxiranes in the presence of β-cyclodextrin and NBS in water

[Arjun Reddy; Bhanumathi; Rama Rao Tetrahedron Letters, 2002 , vol. 43, # 17 p. 3237 - 3238]

Microwave-assisted synthesis of α-hydroxy ketone and α-diketone and pyrazine derivatives from α-halo and α, α′-dibromo ketone

[Utsukihara, Takamitsu; Nakamura, Hiroaki; Watanabe, Masashige; Akira Horiuchi Tetrahedron Letters, 2006 , vol. 47, # 52 p. 9359 - 9364]

Chemo-enzymatic preparation of hydroxymethyl ketones

[Paizs, Csaba; Tosa, Monica; Majdik, Cornelia; Bodai, Viktoria; Novak, Lajos; Irimie, Florin-Dan; Poppe, Laszlo Journal of the Chemical Society. Perkin Transactions 1, 2002 , # 21 p. 2400 - 2402]

Direct α-hydroxylation of aryl ketones using a hypervalent Iodine (III) sulfonate

[Huang; Hou; Wang; Chen Organic Preparations and Procedures International, 2006 , vol. 38, # 5 p. 473 - 476]

Microwave-assisted synthesis of α-hydroxy ketone and α-diketone and pyrazine derivatives from α-halo and α, α′-dibromo ketone

[Utsukihara, Takamitsu; Nakamura, Hiroaki; Watanabe, Masashige; Akira Horiuchi Tetrahedron Letters, 2006 , vol. 47, # 52 p. 9359 - 9364]

More Articles...