Vinylation of aryl bromides using an inexpensive vinylpolysiloxane.
Scott E Denmark, Christopher R Butler
Index: Org. Lett. 8 , 63, (2006)
Full Text: HTML
Abstract
[reaction: see text] A mild and general method for the palladium-catalyzed vinylation of aryl bromides has been developed. The use of tetrabutylammonium fluoride (TBAF) as the activator and an inexpensive and nontoxic vinyl donor, 1,3,5,7-tetramethyl-1,3,5,7-tetravinylcyclotetrasiloxane (D(4)(V), 1), allows for a general and high-yielding preparation of substituted styrenes.
Related Compounds
Related Articles:
Ultrafast cooling reveals microsecond-scale biomolecular dynamics.
2014-01-01
[Nat. Commun. 5 , 5737, (2014)]
2014-10-15
[Small 10(19) , 4020-9, (2014)]
Cracking-assisted photolithography for mixed-scale patterning and nanofluidic applications.
2015-01-01
[Nat. Commun. 6 , 6247, (2015)]
The Influence of a Biologically Relevant Substratum Topography on Human Aortic and Umbilical Vein Endothelial Cells
[Biophys. J. 102 , 1224-1233]