Organic Letters 2010-10-15

Bis-exo-2-norbornylboron triflate for stereospecific enolization of 3,3,3-trifluoropropionates.

P Veeraraghavan Ramachandran, Gowrisankar Parthasarathy, Pravin D Gagare

Index: Org. Lett. 12(20) , 4474-7, (2010)

Full Text: HTML

Abstract

The first boron-mediated enolization-aldolization of 3,3,3-trifluoropropionates has been reported. The preparation and application of bis-exo-bicyclo[2.2.1]heptan-2-ylboron triflate as a superior reagent for diastereospecific enolization has also been described.

Related Compounds

Related Articles:

Self-activation in de novo designed mimics of cell-penetrating peptides.

2011-06-27

[Angew. Chem. Int. Ed. Engl. 50 , 6147, (2011)]

[Establishment of the maximum permissible concentrations of norbornene, norbornadiene and dicyclopentadiene in reservoir water].

1986-02-01

[Gig. Sanit. (2) , 77-9, (1986)]

Pd(II)-catalyzed regioselective 2-alkylation of indoles via a norbornene-mediated C-H activation: mechanism and applications.

2012-09-05

[J. Am. Chem. Soc. 134(35) , 14563-72, (2012)]

A genetically encoded norbornene amino acid for the mild and selective modification of proteins in a copper-free click reaction.

2012-04-27

[Angew. Chem. Int. Ed. Engl. 51(18) , 4466-9, (2012)]

Evaluation of norbornene- beta-cyclodextrin-based monomers and oligomers as chiral selectors by means of nonaqueous capillary electrophoresis.

2001-01-01

[Electrophoresis 22(1) , 109-16, (2001)]

More Articles...