Silica-supported bidentate arsine palladium (0) complex: a highly active and stereoselective catalyst for arylation of conjugated alkenes
M Cai, Y Huang, H Zhao, C Song
Index: Cai, Mingzhong; Huang, Yizheng; Zhao, Hong; Song, Caisheng Journal of Organometallic Chemistry, 2003 , vol. 682, # 1-2 p. 20 - 25
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Citation Number: 28
Abstract
A silica-supported bidentate arsine palladium (0) complex has been prepared from 4-oxa-6, 7-dichloroheptyltriethoxysilane via immobilization on fumed silica, followed by reacting with potassium diphenylarsenide and palladium chloride, and then the reduction with hydrazine hydrate. The complex has been characterized by X-ray photoelectron spectroscopy and it is a highly active and stereoselective catalyst for arylation of styrene and acrylic acid with ...
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