Mn (0)-Mediated Chemoselective Reduction of Aldehydes. Application to the Synthesis of α-Deuterioalcohols
T Jiménez, E Barea, JE Oltra, JM Cuerva…
Index: Jimenez, Tania; Barea, Elisa; Oltra, J. Enrique; Cuerva, Juan M.; Justicia, Jose Journal of Organic Chemistry, 2010 , vol. 75, # 20 p. 7022 - 7025
Full Text: HTML
Citation Number: 11
Abstract
A mild, simple, safe, chemoselective reduction of different kinds of aldehydes to the corresponding alcohols mediated by the Mn dust/water system is described. In addition to this, the use of D2O leads to the synthesis of α-deuterated alcohols and constitutes an efficient, inexpensive alternative for the preparation of these compounds.
Related Articles:
Design, synthesis and anticancer activity evaluation of diazepinomicin derivatives
[Yu, Yongguo; Wu, Jianbo; Lei, Fan; Chen, Lei; Wan, Weili; Hai, Li; Guan, Mei; Wu, Yong Letters in Drug Design and Discovery, 2013 , vol. 10, # 4 p. 369 - 373]
Cyclonerodiol biosynthesis and the enzymic conversion of farnesyl to nerolidyl pyrophosphate
[Cane,D.E.; Iyengar,R.; Shiao,M.S. Journal of the American Chemical Society, 1981 , vol. 103, p. 914]
Synthesis of farnesol isomers via a modified Wittig procedure
[Organic Letters, , vol. 7, # 22 p. 4803 - 4806]
Convergent synthesis of menaquinone-7 (MK-7)
[Sato, Kikumasa; Inoue, Seiichi; Onishi, Akira; Uchida, Nobuhiko; Minowa, Nobuto Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 761 - 769]
Transpeptidase-mediated incorporation of D-amino acids into bacterial peptidoglycan
[Journal of the American Chemical Society, , vol. 133, # 28 p. 10748 - 10751]