Unexpected and then rational synthesis of a new class of anionic phosphino–oxazoline ligands; structure and catalytic properties of a ruthenium complexElectronic …
P Braunstein, F Naud, C Graiff…
Index: Braunstein, Pierre; Naud, Frederic; Graiff, Claudia; Tiripicchio, Antonio Chemical Communications, 2000 , # 11 p. 897 - 898
Full Text: HTML
Citation Number: 13
Abstract
A new class of anionic, hybrid chelating ligands is reported which contain a phosphine moiety covalently linked to an oxazoline of which the nitrogen atom formally carries a partly delocalized negative charge; the first metal complex, a ruthenium derivative, has been characterized by X-ray diffraction and shown to be active in catalytic transfer hydrogenation.
Related Articles:
NHC-stabilized ruthenium nanoparticles as new catalysts for the hydrogenation of aromatics
[Catalysis Science and Technology, , vol. 3, # 1 p. 99 - 105]
Amphiphilic Block Polypeptide??Type Ligands for Micellar Catalysis in Water
[Advanced Synthesis and Catalysis, , vol. 351, # 10 p. 1499 - 1504]
[Tetrahedron, , vol. 61, # 8 p. 2105 - 2109]
[Tetrahedron Letters, , vol. 24, # 38 p. 4139 - 4142]
Emergence of a novel catalytic radical reaction: Titanocene-catalyzed reductive opening of epoxides
[Gansaeuer, Andreas; Bluhm, Harald; Pierobon, Marianna Journal of the American Chemical Society, 1998 , vol. 120, # 49 p. 12849 - 12859]