An iron Schiff base complex loaded mesoporous silica nanoreactor as a catalyst for the synthesis of pyrazine-based heterocycles

R Malakooti, GR Bardajee, S Hadizadeh…

Index: Malakooti, Reihaneh; Bardajee, Ghasem Rezanejade; Hadizadeh, Somayyeh; Atashin, Hassan; Khanjari, Hadiseh Transition Metal Chemistry, 2014 , vol. 39, # 1 p. 47 - 54

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Abstract

Abstract An iron Schiff base complex was encapsulated in SBA-15 mesoporous silica to afford a Fe (III)-Schiff base/SBA-15 heterogeneous nanocatalyst for the synthesis of pyridopyrazine and quinoxaline heterocycles. These reactions proceeded in water with excellent yields. The catalyst was characterized by physico-chemical and spectroscopic methods and found to retain the characteristic channel structures of the SBA-15, allowing ...

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