Trifluoromethyl triflate: synthesis and reactions.
SL Taylor, JC Martin
Index: Taylor, S. L.; Martin, J. C. Journal of Organic Chemistry, 1987 , vol. 52, # 19 p. 4147 - 4156
Full Text: HTML
Citation Number: 31
Abstract
A new and convenient synthesis of trifluoromethyl trifluoromethanesulfonate (trifluoromethyl triflate, TFMT) has been devised. The addition of triflic anhydride to a catalytic amount of antimony pentafluoride at 25" C produces TFMT in 94% yield, utilizing a new and stronger Lewis acid catalyst produced in the reaction, F4SbOS02CF3. This reaction makes pure TFMT conveniently and economically available in large quantities. A mechanism is ...
Related Articles:
CrOX-Y2O3 catalysts for vapor phase fluorination of dichlorodifluoromethane
[Jia, Wen-Zhi; Xing, Li-Qiong; Qian, Lin; Chen, Xin; Wang, Yue-Juan; Lu, Ji-Qing; Chen, Ke-Feng; Zhang, Xue-Liang; Luo, Meng-Fei Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry, 2010 , vol. 49, # 9 p. 1212 - 1216]
[Journal of Fluorine Chemistry, , vol. 156, p. 378 - 381]
[Journal of the American Chemical Society, , vol. 63, p. 789]
Reaction between carbon dioxide and elementary fluorine
[Journal of Fluorine Chemistry, , vol. 128, # 1 p. 17 - 28]
[Journal of the American Chemical Society, , vol. 63, p. 2793]