Inorganic Chemistry

Preparation and Properties of Tetracoördinate Sulfur (IV) Fluorides

RM Rosenberg, EL Muetterties

Index: Rosenberg, R. M.; Muetterties, E. K. Inorganic Chemistry, 1962 , vol. 1, p. 756 - 762

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Citation Number: 47

Abstract

The new perfluoroalkpl derivatives of SF4,[(CF3hCF]? SF?,(CFa) 2CFSF3, and (CF3)* CFSF2CF3 have been prepared by the addition of SF4 and CF3SFa to CF3-CF= CF2. Investigation of their chemistry has led to the preparation of (CF,) KFSF,(CF,) L! FSOCF (CFa)*,(CFa)? CFS (O) OH, and (CF3) 2CFS (0) OCH2CH,.

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