Efficient synthesis of α-(fluoro/chloro/methoxy) disulfonylmethane derivatives as tunable substituted methyl synthons via a new C–S bond forming strategy
GKS Prakash, F Wang, C Ni, TJ Thomas…
Index: Prakash, G.K. Surya; Wang, Fang; Ni, Chuanfa; Thomas, Tito Joe; Olah, George A. Journal of Fluorine Chemistry, 2010 , vol. 131, # 10 p. 1007 - 1012
Full Text: HTML
Citation Number: 8
Abstract
A new synthetic protocol for the preparation of α-fluoro (disulfonyl) methane and its chloro as well as methoxy analogues has been developed. Due to the synthetic utility of α-fluoro (bisphenylsulfonyl) methane (FBSM) as a versatile synthon in the preparation of various useful fluoromethylated organic molecules, search for an easy and economic for its preparation route has been essential. The C–S bond forming strategy is utilized in this ...
Related Articles:
Mono and difluorination of centers α to sulfonates and phosphonates using AcOF
[Vints, Inna; Gatenyo, Julia; Rozen, Shlomo Journal of Fluorine Chemistry, 2013 , vol. 146, p. 66 - 69]
[Ni, Chuanfa; Zhang, Laijun; Hu, Jinbo Journal of Organic Chemistry, 2009 , vol. 74, # 10 p. 3767 - 3771]
Regioselective electrochemical monofluorination of α-sulfonyl sulfides
[Nagura, Hirokatsu; Fuchigami, Toshio Synlett, 2008 , # 11 p. 1714 - 1718]
[Prakash, G.K. Surya; Shao, Nan; Wang, Fang; Ni, Chuanfa Organic Syntheses, 2013 , vol. 90, p. 130 - 144]
[Prakash, G.K. Surya; Shao, Nan; Wang, Fang; Ni, Chuanfa Organic Syntheses, 2013 , vol. 90, p. 130 - 144]