Molecules 2010-07-01

Synthesis, characterization and reactivity ratio study of poly(di(tri-n-butyltin) citraconate-co-N-vinylimidazole).

Salem S Al-Deyab, Mohamed H El-Newehy, Ali M Al-Hazmi

Index: Molecules 15(7) , 4750-6, (2010)

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Abstract

The organotin monomer di(tri-n-butyltin) citraconate (DTBTC, I) was synthesized. Subsequently this monomer was copolymerized with N-vinylimidazole (VI) using a free radical technique. The overall conversion was kept low (< or = 14% wt/wt) for all studied samples and the copolymer composition was determined from tin analysis using the Gilman and Rosenberg method. The synthesized monomer and copolymer were further characterized by elemental analysis, (1)H- and (13)C-NMR, and FTIR spectroscopy.


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