Tetrahedron

Photochemistry of reactive surface-active compounds in adsorbed monolayers

DA Holden, JW Taylor, D Clausen

Index: Holden, David A.; Taylor, Joseph W.; Clausen, Diane Tetrahedron, 1987 , vol. 43, # 7 p. 1671 - 1678

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Citation Number: 5

Abstract

The reactions of long-chain diazo ketones and azides in adsorbed monolayers on inorganic solids were investigated and compared with the corresponding behaviour in monolayers at the air-water interface. The isolated products indicate that reaction of photochemically generated intermediates occurs both with co-adsorbed water and with hydroxyl groups on the solid surface. In the case of 1-diazo-2-oxoheptadecane, for example, the products of ...