Reactions of Silane with Unsaturated Hydrocarbons

DG White, EG Rochow

Index: White; Rochow Journal of the American Chemical Society, 1954 , vol. 76, p. 3897,3899

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Citation Number: 37

Abstract

TABLE IV SUMMARY OF CONSTANTS Reaction )I - 2.00 100 250 40' ... UO$+ + NOa- UOtNOt+ 0.30 0.24 0.17 UOz++ + so4 = Uolsol 63 76 96 UO2 + + HSOd- = UOISO~ + H + 6.1 6.4 6.5 UOr+++ 2SO4 = UOz(S0c)t- 5.8 X 102 7.1 X lo2 8.2 X lo2 UOz++ + HF UOiF' + H + 56 26 21 250, $I = 0.05 0.25 0.50 1.00 GO?++ + HF = UOsF 4- H 51 37 24 27 TABLE V FREE ENERGY, HEAT CONTENT AND ENTROPY CHANGES AT 25', IONIC STRENGTH 2.00, FOR THE REACTIONS: ...