Acta Crystallographica Section E 2011-11-01

Dichlorido(furfuryl-amine-κN)(η-hexa-methyl-benzene)-ruthenium(II).

Amine Garci, Trieu-Tien Thai, Georg Süss-Fink, Bruno Therrien

Index: Acta Crystallogr. Sect. E Struct. Rep. Online 67(Pt 11) , m1592, (2011)

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Abstract

The single-crystal X-ray structure analysis of [RuCl(2)(C(12)H(18))(C(5)H(7)NO)] reveals a distorted piano-stool geometry around the Ru(II) atom, with a hexa-methyl-benzene ligand, two chloride ligands and a furfuryl-amine ligand, the latter coordinating through the amine group. In the crystal, a dimeric structure is observed as a result of N-H⋯Cl inter-actions between two symmetry-related mol-ecules.


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