Tetrahedron letters

Reductive cleavage of resin bound arylsulfonates

S Jin, DP Holub, DJ Wustrow

Index: Jin, Shujuan; Holub, David P.; Wustrow, David J. Tetrahedron Letters, 1998 , vol. 39, # 22 p. 3651 - 3654

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Citation Number: 36

Abstract

A 4-hydroxybenzoate was tethered to a solid support via an arylsulfonate bond. The carboxylate functionality was converted to a variety of esters and amides. The products were then liberated from the resin by Pd (0) catalyzed reductive cleavage of the arylsulfonate oxygen.

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