Novel silylation of aromatic nitriles via photo-induced electron transfer
S Kyushin, Y Ehara, Y Nakadaira…
Index: Kyushin, Soichiro; Ehara, Yasushi; Nakadaira, Yasuhiro; Ohashi, Mamoru Journal of the Chemical Society, Chemical Communications, 1989 , # 5 p. 279 - 280
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Citation Number: 25
Abstract
Photo-induced electron transfer reactions of hexamethyldisilane and aromatic nitriles have been examined; hexamethyldisilane acts as an effective a-donor, and undergoes novel photochemical silylation of aromatic nitriles. ... Photo-induced electron transfer reactions of good electron accepting aromatic nitriles have been studied extensively,1 and various types of electron donors have been employed: ie, n-donors such as aromatic compounds,2 ethylene derivatives,3 and ally1 ...
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