Organic & Biomolecular Chemistry 2009-04-07

Isolation of the key intermediates in the catalyst-free conversion of oxiranes to thiiranes in water at ambient temperature.

Christian M Kleiner, Luise Horst, Christian Würtele, Raffael Wende, Peter R Schreiner

Index: Org. Biomol. Chem. 7(7) , 1397-403, (2009)

Full Text: HTML

Abstract

Herein we shed light on the mechanism of the reaction of epoxides with ammonium thiocyanate to give the corresponding thiiranes in water, and we present a computational mechanistic model for this highly useful reaction.

Related Compounds

Related Articles:

Development of ultrasound-assisted emulsification microextraction for determination of thiocynate ion in human urine and saliva samples.

2013-02-15

[J. Chromatogr. B. Analyt. Technol. Biomed. Life Sci. 917-918 , 5-10, (2013)]

In vitro investigations on the effect of dermal fibroblasts on keratinocyte responses to ultraviolet B radiation.

2014-01-01

[Photochem. Photobiol. 90(6) , 1332-9, (2014)]

Oral administration of paeoniflorin attenuates allergic contact dermatitis by inhibiting dendritic cell migration and Th1 and Th17 differentiation in a mouse model.

2015-04-01

[Int. Immunopharmacol. 25(2) , 432-9, (2015)]

Mechanisms of chemical cooperative carcinogenesis by epidermal Langerhans cells.

2015-05-01

[J. Invest. Dermatol. 135(5) , 1405-14, (2015)]

Effect of lyophilization on liposomal encapsulation of salmon calcitonin.

2014-12-01

[J. Liposome Res. 24(4) , 297-303, (2014)]

More Articles...