STUDIES ON ORGANOPHOSPHORUS COMPOUNDS XXXI. ALKALINE HYDROLYSIS OF 2-ALKYL-2-OXO-1, 3, 2-DIOXA-PHOSPHORINANE AND-PHOSPHEPANE

C Yuan, S Li, X Liao

Index: Yuan, Chengye; Li, Shusen; Liao, Xiugao Phosphorus and Sulfur and the Related Elements, 1988 , vol. 37, p. 205 - 212

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Citation Number: 5

Abstract

Abstract Alkaline hydrolysis of 2-alkyl-2-oxo-1, 3, 2-dioxaphosphorinane and-phosphepane was studied in aqueous dioxane. The rate constants were determined at various temperature and the activation parameter of the reaction were evaluated. The hydrolytic process is classified as a AE reaction. Quantitative structure-reactivity relationship was examined by multiple regression analysis involving the rate constants and the structural ...