Cross-coupling reaction of pentacoordinate alkenylsilicates with organic halides and triflates catalyzed by a palladium complex

…, C Murakami, H Aihara, E Komori, S Kohra…

Index: Hojo, Makoto; Murakami, Chikara; Aihara, Hidenori; Komori, Ei-ichi; Kohra, Shinya; et al. Bulletin de la Societe Chimique de France, 1995 , vol. 132, p. 499 - 508

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Citation Number: 18

Abstract

Résumé/Abstract Isolated pentacoordinate alkoxy-substituted alkenylsilicates, are readily prepared by mixing alkenyltrialkoxy-silane, catechol and triethylamine at room temperature. Cross-coupling reactions of these alkenylsilicates with organic halides or triflates are catalyzed by a palladium complex and proceed very smoothly and cleanly to give the corresponding alkenes. The cross-coupling reactions could be also attained by a one pot ...