Nickel-catalyzed hydrodehalogenation of aryl halides

M Weidauer, E Irran, CI Someya, M Haberberger…

Index: Weidauer, Maik; Irran, Elisabeth; Someya, Chika I.; Haberberger, Michael; Enthaler, Stephan Journal of Organometallic Chemistry, 2013 , vol. 729, p. 53 - 59

Full Text: HTML

Citation Number: 16

Abstract

In the present study, the nickel-catalyzed dehalogenation of aryl and alkyl halides with iso- propyl zinc bromide or tert-butylmagnesium chloride has been examined in detail. With a straightforward nickel complex as pre-catalyst good to excellent yields and chemoselectivities were feasible for a variety of aryl and alkyl halides.

Related Articles:

Novel multi-chalcogen ring systems with three different chalcogen atoms: synthesis, structure and redox property of five-membered trichalcogenaheterocycles

[Ogawa, Satoshi; Yoshimura, Satoko; Nagahora, Noriyoshi; Kawai, Yasushi; Mikata, Yuji; Sato, Ryu Chemical Communications, 2002 , # 17 p. 1918 - 1919]

Iron??Catalyzed Oxidative Heterocoupling Between Aliphatic and Aromatic Organozinc Reagents: A Novel Pathway for Functionalized Aryl–Alkyl Cross??Coupling …

[Cahiez, Gerard; Foulgoc, Laura; Moyeux, Alban Angewandte Chemie, International Edition, 2009 , vol. 48, # 16 p. 2969 - 2972]

Carbon-Based Leaving Group in Substitution Reactions: Functionalization of sp3-Hybridized Quaternary and Tertiary Benzylic Carbon Centers

[Mahoney, Stuart J.; Lou, Tiantong; Bondarenko, Ganna; Fillion, Eric Organic Letters, 2012 , vol. 14, # 13 p. 3474 - 3477]

Nickel??Catalyzed Kumada Reaction of Tosylalkanes with Grignard Reagents to Produce Alkenes and Modified Arylketones

[Wu, Ji-Cheng; Gong, Lu-Bing; Xia, Yuanzhi; Song, Ren-Jie; Xie, Ye-Xiang; Li, Jin-Heng Angewandte Chemie - International Edition, 2012 , vol. 51, # 39 p. 9909 - 9913]

An expedient synthesis of isopropyl anisoles and veratroles

[Yli-Kauhaluoma, Jari T.; Janda, Kim D. Tetrahedron Letters, 1994 , vol. 35, # 26 p. 4509 - 4510]

More Articles...