The synthesis of α, ω-disubstituted higher alkanes from α, α, α, ω-tetrachloroalkanes
K Saotome, H Komoto, T Yamazaki
Index: Saotome,K. et al. Bulletin of the Chemical Society of Japan, 1966 , vol. 39, p. 480 - 484
Full Text: HTML
Citation Number: 16
Abstract
Higher ω-chloroalkanoic acids than ω-chlorooctanoic acid were prepared in good yields (over 90%) by improved methods of the hydrolysis of α, α, α, ω-tetrachloroalkanes. The reactions were carried out in fuming nitric acid, with the addition of nitrogen dioxide during the reaction or in the presence of a small amount of phosphoric anhydride. α, ω- Dichloroalkanes were derived from the ω-chloroalkanoic acids by the Kolbe electrolytic ...
Related Articles:
Synthesis of phospholipids suitable for covalent binding to surfaces
[Kallury, R. Krishnamohanrao; Krull, Ulrich J.; Thompson, Michael Journal of Organic Chemistry, 1987 , vol. 52, # 24 p. 5478 - 5480]
Osmium tetroxide-promoted catalytic oxidative cleavage of olefins: an organometallic ozonolysis
[Travis, Benjamin R.; Narayan, Radha S.; Borhan, Babak Journal of the American Chemical Society, 2002 , vol. 124, # 15 p. 3824 - 3825]
Preparation of ω-hydroxynonanoic acid and its ester derivatives
[Kula, Jozef; Smigielski, Krzysztof; Quang, Thuat B.; Grzelak, Iwona; Sikora, Magdalena JAOCS, Journal of the American Oil Chemists' Society, 1999 , vol. 76, # 7 p. 811 - 817]
[Wiberg, Kenneth B.; Waldron, Roy F. Journal of the American Chemical Society, 1991 , vol. 113, # 20 p. 7697 - 7705]
Omega-hydroxy aliphatic acids. Synthesis of sabinic acid
[Lycan; Adams Journal of the American Chemical Society, 1929 , vol. 51, p. 627]