Structure of chlorobis (dicyclohexylphenylphosphine) gold (I)

…, SI Cuadrado, JA Muir, CL Barnes

Index: Muir, Mariel M.; Cuadrado, Sandra I.; Muir, James A.; Barnes, Charles L. Acta Crystallographica, Section C: Crystal Structure Communications, 1988 , vol. 44, p. 1659 - 1660

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Citation Number: 5

Abstract

Abstract.[AuCI {(C6HII) 2 (C6Hs) P} 2], Mr= 781-2, monoclinic, P2l, a= 11.117 (4), b= 13.606 (5), c= 12.284 (4) A, fl= 109.59 (3), V= 1753 (2) A3, Z= 2, Dx= l. 48gcm-3, 2 (MoKc0= 0.71073 A,/~= 43.8 cm-~, F (000)= 792, T= 296 K, final R= 0.024 for 3239 unique observed reflections. The formation of complexes of the type LnAuX, where L is a phosphine, and X is halide or pseudohalide, shows considerable dependence on the nature of the phosphine. ...