Quantitative determination of lead in mixtures of lead(II) halides using solid-state 207Pb NMR spectroscopy.

Alicia Glatfelter, Nicole Stephenson, Shi Bai, Cecil Dybowski, Dale L Perry

Index: Analyst 131(11) , 1207-9, (2006)

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Abstract

We demonstrate a multi-spectrum technique for facile, quantitative determination of lead in solid materials using solid-state (207)Pb NMR that avoids the major problem of uniform excitation across a wide spectral range; the method can be employed without chemical separation or other chemical manipulations and without any prior sample preparation, resulting in a non-destructive analysis, and producing results that are in agreement with gravimetric analyses of mixed samples of the lead halides.