Palladium-catalyzed cocyclization of arynes with alkynes: Selective synthesis of phenanthrenes and naphthalenes

…, D Pérez, E Guitián, L Castedo

Index: Pena, Diego; Perez, Dolores; Guitian, Enrique; Castedo, Luis Journal of the American Chemical Society, 1999 , vol. 121, # 24 p. 5827 - 5828

Full Text: HTML

Citation Number: 176

Abstract

Reactions mediated by transition metals have played a crucial role in the development of synthetic methodology during the last quarter of this century. A paradigm of the synthetic potential of these transformations is the metal-catalyzed cyclotrimerization of alkynes to afford aromatic compounds. 1 This extensively exploited reaction has been studied from the mechanistic point of view and has been expanded in scope to embrace cocyclizations of ...

Related Articles:

Mechanisms and reactivity differences for cycloaddition of anhydride to alkyne catalyzed by palladium and nickel catalysts: insight from density functional calculations

[Jafarpour, Farnaz; Hazrati, Hamideh; Nouraldinmousa, Sorour Organic Letters, 2013 , vol. 15, # 15 p. 3816 - 3819]

Salt/ligand-activated low-valent titanium formulations: the 'salt effect'on diastereoselective carbon–carbon bond forming SET reactions

[Rele, Shyam M.; Nayak, Sandip K.; Chattopadhyay, Subrata Tetrahedron, 2008 , vol. 64, # 30-31 p. 7225 - 7233]

Generation of benzocyclobutadiene derivatives from zirconaindene derivatives

[Chen, Chao; Xi, Chanjuan; Liu, Yuanyuan; Hong, Xiaoyin Journal of Organic Chemistry, 2006 , vol. 71, # 14 p. 5373 - 5376]

Metal-ammonia reduction. VII. Stereospecific reduction in the phenanthrene series

[Rabideau,P.W.; Harvey,R.G. Journal of Organic Chemistry, 1970 , vol. 35, p. 25 - 30]

Metal-ammonia reduction. VII. Stereospecific reduction in the phenanthrene series

[Rabideau,P.W.; Harvey,R.G. Journal of Organic Chemistry, 1970 , vol. 35, p. 25 - 30]

More Articles...