Photochemical Reactions of Dicyanobenzenes with Aliphatic Amines

M Ohashi, K Miyake, K Tsujimoto

Index: Ohashi, Mamoru; Miyake, Kentaro; Tsujimoto, Kazuo Bulletin of the Chemical Society of Japan, 1980 , vol. 53, # 6 p. 1683 - 1688

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Citation Number: 44

Abstract

Upon irradiation, p-dicyanobenzene reacted with primary, secondary, and tertiary aliphatic amines to give substitution products in which one of the cyano groups was replaced by the amine at α-CH position or by an alkyl group of the amine. o-Dicyanobenzene reacted similarly, but the meta-isomer did not react under similar conditions. The rates of the fluorescence quenching of p-dicyanobenzene with the amines are close to the ...