Artifact formation during gas chromatographic-mass spectrometric analysis of a methylsulfinyl-containing metabolite.
J K Huwe
Index: J. Chromatogr. A. 575(2) , 287-8, (1992)
Full Text: HTML
Abstract
During gas chromatographic-mass spectrometric analysis using a heated injector, 1-methylthio-4-methylsulfinyltetrachlorobenzene degraded to form tetrachlorothioanisole. Similar reductive defunctionalizations have been reported during in vivo metabolisms. Caution should be used to distinguish metabolites from artifacts which may be formed during the analysis of methylsulfoxides.
Related Compounds
Related Articles:
Comparison of bifunctional chelates for (64)Cu antibody imaging.
2010-11-01
[Eur. J. Nucl. Med. Mol. Imaging 37(11) , 2117-26, (2010)]
(68)Ga small peptide imaging: comparison of NOTA and PCTA.
2012-11-21
[Bioconjug. Chem. 23(11) , 2239-46, (2012)]
The metabolism of pentachloromethylthiobenzene in germ-free and conventional rats.
1981-03-01
[Xenobiotica 11(3) , 173-8, (1981)]
1980-01-01
[Dev. Toxicol. Environ. Sci. 8 , 627-30, (1980)]
1981-01-01
[Nutr. Cancer 2(4) , 224-31, (1981)]