Boron trifluoride promoted reaction of alkyl hypohalites with alkenes. A new synthesis of fluoro halides
…, ML Oakes, DF Shellhamer, GE Heasley…
Index: Heasley, Victor L.; Gipe, Robert K.; Martin, Jody L.; Wiese, Harry C.; Oakes, Melanie L.; Shellhamer, Dale F. Journal of Organic Chemistry, 1983 , vol. 48, # 19 p. 3195 - 3199
Full Text: HTML
Citation Number: 32
Abstract
The reactions of the following alkenes with alkyl hypohalites and boron trifluoride (BF,) were investigated: cyclohexene (3), 1-hexene (8), trans-1, 2-dichloroethylene (15), methyl acrylate (l8), methyl crotonate (25), methyl isocrotonate (29), butadiene (33), methyl vinyl ketone (42), and styrene (45). Reactions of these alkenes with methyl hypochlorite (1) and BF3 in dichloromethane give fluoro chloride adducts as well as methoxy chlorides with the ...
Related Articles:
[Heasley, Victor L.; Wade, Kimberley E.; Aucoin, Thomas G.; Gipe, Daphne E.; Shellhamer Dale F.; Heasley, Gene E. Journal of Organic Chemistry, 1983 , vol. 48, # 8 p. 1377 - 1379]
Amino acids; 13: Investigations on the synthesis of dl-serine from α-haloacrylic acid derivatives
[Effenberger, Franz; Zoller, Gerhard Tetrahedron, 1988 , vol. 44, # 17 p. 5573 - 5582]
N-Substituted amino acid N′-benzylamides: Synthesis, anticonvulsant, and metabolic activities
[Beguin, Cecile; LeTiran, Arnaud; Stables, James P.; Voyksner, Robert D.; Kohn, Harold Bioorganic and Medicinal Chemistry, 2004 , vol. 12, # 11 p. 3079 - 3096]