A Simple Regioselective Nuclear Bromination of Alkyl Phenyl Ethers

S Yakabe, M Hirano, T Morimoto

Index: Yakabe, Shigetaka; Hirano, Masao; Morimoto, Takashi Organic Preparations and Procedures International, 1998 , vol. 30, # 2 p. 218 - 222

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Abstract

14 6 110 7 90 135-136/10 140/12k 15" 8 80 9 86 94-96/0.5 97/0.5'a) At 20", under argon; ether 1 mmol, NaCIO, 1.25 mmol, NaBr 2 mmol, Mn (acac), 0.01 mmol, moist alumina 1 g, hexane 10 mL. b) Yield of chromatographically purified product based on the starting ether. c) 13% of 4g was recovered. 6) NaClO, 1 mmol. e) Beilstein, 6, II, 185.8 Beilstein,

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