Studies of the generation of excited singlet products in the oxidation of the-CO-CH-containing molecules. The chemiluminescence of acylcarbazoles.

I Kamiya, T Sugimoto

Index: Kamiya, Isao; Sugimoto, Takashi Bulletin of the Chemical Society of Japan, 1981 , vol. 54, # 1 p. 25 - 30

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Citation Number: 6

Abstract

Direct chemiluminescence emissions have been found from the air oxidation of 3-acyl-9- methyl-(1), 3, 6-diacyl-9-methyl-(2), and 9-acylcarbazoles (3) due to the generation of an excited singlet state of monocarboxylate ions (from 1 and 2) and the carbazole anion (from 3). The relative intensities vs. the reaction time for the luminescent reaction of 3-isobutyryl-9- methylcarbazole could be interpreted by a reaction scheme involving consecutive ...