Acta Crystallographica, Section C: Crystal Structure Communications 2004-09-01

Tetraaqua(3,4,7,8-tetramethyl-1,10-phenanthroline-kappa2N,N')zinc(II) thiosulfate.

M Enriqueta Díaz de Vivar, Sergio Baggio, Andrés Ibañez, Ricardo Baggio

Index: Acta Crystallogr. C 60(Pt 9) , m451-3, (2004)

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Abstract

In the title complex of zinc(II) with 3,4,7,8-tetramethyl-1,10-phenanthroline (tmph), viz. [Zn(C16H16N2)(H2O)4](S2O3), the metal atom has a monomeric octahedral ZnN2O4 complex environment comprising two N-atom donors from the tmph group and four aqua O-atom donors. The complex cation is connected to four thiosulfate anions through a compact hydrogen-bonding network involving all coordinated aqua H-atom donors and all the outer acceptors (O and S) of the anion.

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